OXIDATION REACTIONS CATALYZED BY TITANIUM-CONTAINING AND CHROMIUM-CONTAINING SILICALITES

Authors
RAJU SVN UPADHYA TT PONRATHNAM S DANIEL T SUDALAI A
Citation
Svn. Raju et al., OXIDATION REACTIONS CATALYZED BY TITANIUM-CONTAINING AND CHROMIUM-CONTAINING SILICALITES, Chemical communications, (16), 1996, pp. 1969-1970
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
16
Year of publication
1996
Pages
1969 - 1970
Database
ISI
SICI code
1359-7345(1996):16<1969:ORCBTA>2.0.ZU;2-S
Abstract
While the titanium silicalite-1 (TS-1)-tert-butyl hydroperoxide (TBHP) combination exhibits remarkable activity and selectivity in the oxida tive cleavage of the C-C double bond of silyl enol ethers to produce d icarboxylic acids, the chemoselective oxidation of thioethers to sulfo xides without generation of sulfones is achieved using chromium silica lite-2 (CrS-2)-H2O2.