KINETICS OF THERMAL-DECOMPOSITION OF FESO4-CENTER-DOT-7H(2)O

Citation
J. Straszko et al., KINETICS OF THERMAL-DECOMPOSITION OF FESO4-CENTER-DOT-7H(2)O, Inzynieria Chemiczna i Procesowa, 17(3), 1996, pp. 517-528
Citations number
8
Categorie Soggetti
Engineering, Chemical
ISSN journal
02086425
Volume
17
Issue
3
Year of publication
1996
Pages
517 - 528
Database
ISI
SICI code
0208-6425(1996)17:3<517:KOTOF>2.0.ZU;2-X
Abstract
Thermogravimetry, derivative thermogravimetry (TG-DTG), and differenti al thermal analysis (DTA) have been used in the study of decomposition of hydrated ferrous (II) sulphate under air atmosphere. The kinetics of particular stages of FeSO4 . 7H(2)O decomposition were evaluated fr om the dynamic weight losses data. The values of the activation energy E, the preexponential factor A, and thermodynamic parameters of the e ach stages of the thermal decomposition were calculated from alpha(t) data by using the integral method by the applying the Coats-Redferns a pproximation.