SPECTROSCOPIC PROPERTIES OF HCL ADDUCTS O F THE DI(PHTHALOCYANINATO(2-))LANTHANIDE ACIDS

Authors
OSTENDORP G HOMBORG H
Citation
G. Ostendorp et H. Homborg, SPECTROSCOPIC PROPERTIES OF HCL ADDUCTS O F THE DI(PHTHALOCYANINATO(2-))LANTHANIDE ACIDS, Zeitschrift fur anorganische und allgemeine Chemie, 622(8), 1996, pp. 1415-1418
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
622
Issue
8
Year of publication
1996
Pages
1415 - 1418
Database
ISI
SICI code
0044-2313(1996)622:8<1415:SPOHAO>2.0.ZU;2-K
Abstract
Thin films of iminiumdi(phthalocyaninato(2-))lanthanidates(III), (PNP) [Ln(Pc(2-))(2)] (Ln = La...(-Ce, Pm)...Lu) react with hydrogen chlorid e yielding the green acid adduct [HLn(Pc(2-))(2)]. xHCl. The typical p i-pi transitions of the Pc(2-) ligand are observed in the UV-VIS spec tra (B: similar to 14500 cm(-1); Q: similar to 30300 cm(-1)); these ar e broadened and shifted to lower energy with respect to those of the p recursor. A N-H stretching vibration at similar to 3170 cm(-1) as well as a H-N-C deformation vibration at similar to 1200 cm(-1) in the MIR spectra are diagnostic for these HCl adducts.