Zero-field muon spin relaxation and resistivity experiments on La0.67C
a0.33MnO3 powder show that the sublattice magnetization nu(mu)(T) is w
ell described for T less than or equal to T-c by (1 - T/T-c)(beta), wh
ere beta = 0.345 +/- 0.015, characteristic of a second-order phase tra
nsition for a 3D spin system, and the ferromagnetic transition tempera
ture (T-c = 274 K) and resistivity peak temperature coincide to within
1 K. Below T-C nu(mu) and the zero-field resistivity rho are correlat
ed, with nu(mu) proportional to - ln rho. Unusual relaxational dynamic
s suggest spatially inhomogeneous Mn-ion correlation times. These resu
lts are discussed in terms of the possible effects of polarons on the
spin and charge dynamics.