FORMATION OF AN ANIONIC TITANIUM(IV) SULFIDE DIMER, (NA-2[CPTI(MU-S)(S)](2)CENTER-DOT-4THF)(2), BY ELIMINATION OF CPH AND H-2 FROM CP(2)TI(SH)(2) UPON DEPROTONATION WITH NAH

Authors
LUNDMARK PJ KUBAS GJ SCOTT BL
Citation
Pj. Lundmark et al., FORMATION OF AN ANIONIC TITANIUM(IV) SULFIDE DIMER, (NA-2[CPTI(MU-S)(S)](2)CENTER-DOT-4THF)(2), BY ELIMINATION OF CPH AND H-2 FROM CP(2)TI(SH)(2) UPON DEPROTONATION WITH NAH, Organometallics, 15(17), 1996, pp. 3631-3633
Citations number
45
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
17
Year of publication
1996
Pages
3631 - 3633
Database
ISI
SICI code
0276-7333(1996)15:17<3631:FOAATS>2.0.ZU;2-G
Abstract
A deprotonation. reaction of Cp(2)Ti(SH)(2) with NaH in THF yields {Na -2[CpTi(mu-S)(S)](2) . 4THF}(2), generated by unexpected elimination o f CpH. This anionic dimer is unique in that it is the first organomtal lic titanium species containing terminal sulfido ligands. The latter a re stabilized by interactions with THF-solvated sodium cations, thus i mposing a syn Ti=S configuration.