HYDROXYL RADICAL-INDUCED REACTIONS WITH 1-BROMO-2-FLUOROBENZENE IN AQUEOUS-SOLUTIONS - FORMATION OF RADICAL CATIONS

Authors
MOHAN H MITTAL JP
Citation
H. Mohan et Jp. Mittal, HYDROXYL RADICAL-INDUCED REACTIONS WITH 1-BROMO-2-FLUOROBENZENE IN AQUEOUS-SOLUTIONS - FORMATION OF RADICAL CATIONS, Chemical physics letters, 263(1-2), 1996, pp. 263-270
Citations number
31
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
263
Issue
1-2
Year of publication
1996
Pages
263 - 270
Database
ISI
SICI code
0009-2614(1996)263:1-2<263:HRRW1I>2.0.ZU;2-S
Abstract
Hydroxyl radicals are observed to react with 1-bromo-2-fluorobenzene t o form C6H4BrF . OH and (C6H4BrF)(+.) in neutral and acidic solutions respectively. The nature and reactivity of the solute radical cation, (C6H4BrF)(+.), formed under different acidic conditions are discussed.