High phase purity (Hg,Re)Ba2Ca1Cu2Oy and (Hg,Re)Ba2Ca2Cu3Oy supercondu
ctors were prepared from commercially available Ba2Can-1CunOx precurso
rs, HgO, and Re2O7. The addition of Re was found to have beneficial ef
fects on the phase formation and chemical stability of the superconduc
ting materials. Optimal annealing temperatures were found to be above
880 degrees C for the (Hg,Re)Ba2Ca2Cu3Oy phase and below 850 degrees C
for the (Hg,Re)Ba2Ca1Cu2Oy phase. The microstructure of the samples i
s dominated by high density island-like superconducting areas intercon
nected by low density superconducting material and second phases. The
randomly oriented platelike superconducting grains are typically aroun
d 5 mu m thick and up to 100 mu m long. Investigations of (Hg,Re)Ba2Ca
2Cu3Oy samples quenched from various annealing stages indicate that th
e (Hg,Re)Ba2Ca2Cu3Oy phase forms via the (Hg,Re)Ba2Ca1Cu2Oy phase and
is assisted by a liquid phase on a microscopic length scale.