The formation process of metastable dt mu molecules in D-2-T-2 mixture
s is investigated. The dt mu molecule exhibits a series of three-body
resonances embedded in the t mu+d scattering continuum just below the
t mu(2s)+d threshold, These states can-be formed in collisions of exci
ted t mu(2s) atoms with D-2 molecules, whereby the excess of binding e
nergy is absorbed by the rovibrational degrees of freedom of D-2. We p
resent a scattering-theoretic model for this process, and perform a nu
merical calculation of its cross section. The essential transition amp
litudes are obtained from three-body wave functions for the dt mu subc
luster, and adiabatic wave functions for the entire hybrid system in t
he final channel. It is found that the effective formation rate is lim
ited by the Auger-transition rates of the molecular complex formed. Th
e calculated cross sections exhibit broad ''peaks,'' with magnitudes l
arge enough for the formation process to favorably compete with deexci
tation of t mu(n=2) atoms via radiative and collisional processes. The
formation of metastable dt mu can therefore be one of the fastest pro
cesses depleting the n=2 levels of the t mu atom in hydrogen mixtures,
of importance for low-energy muon science, electroweak physics, and m
uon catalyzed fusion.