ALLYL RHODIUM(III) COMPLEXES CONTAINING HETEROCYCLIC NITROGEN LIGANDS

Authors
PASTERNAK H PRUCHNIK FP
Citation
H. Pasternak et Fp. Pruchnik, ALLYL RHODIUM(III) COMPLEXES CONTAINING HETEROCYCLIC NITROGEN LIGANDS, Transition metal chemistry, 21(4), 1996, pp. 305-308
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
21
Issue
4
Year of publication
1996
Pages
305 - 308
Database
ISI
SICI code
0340-4285(1996)21:4<305:ARCCHN>2.0.ZU;2-6
Abstract
A series of hexacoordinated Rh-III complexes of general formula trans- [RhCl2(allyl)(N-N)] (allyl = C3H5 or C4H7; N-N = 1,10-phenanthroline, 2,9-dimethyl-1,10-phenanthroline, 4,7-diphenyl-1,10-phenanthroline, 2, 2'-bipyridine or 4,4'-dimethyl-2,2'-bipyridine) have been synthesized and characterized by spectroscopic methods. The complexes have an octa hedral geometry with the Cl ligands coordinated in the trans positions . The catalytic activity of [RhCl2(C4H7)(phen)] with respect to hydrog enation of alkenes has been investigated.