NEUTRAL AND CATIONIC NICKEL(II) COMPLEXES OF PHOSPHINO-AMINES - [NICL2(PME(2)PH)(PNME(2))] AND [NICL(PME(2)PH)(PNME(2))]PF6 NME(2)=N,N'-DIMETHYL-2-(DIPHENYLPHOSPHINO)ANILINE)

Authors
CROCIANI L REFOSCO F TISATO F GATTO S CORAIN B
Citation
L. Crociani et al., NEUTRAL AND CATIONIC NICKEL(II) COMPLEXES OF PHOSPHINO-AMINES - [NICL2(PME(2)PH)(PNME(2))] AND [NICL(PME(2)PH)(PNME(2))]PF6 NME(2)=N,N'-DIMETHYL-2-(DIPHENYLPHOSPHINO)ANILINE), Inorganica Chimica Acta, 249(2), 1996, pp. 131-133
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
249
Issue
2
Year of publication
1996
Pages
131 - 133
Database
ISI
SICI code
0020-1693(1996)249:2<131:NACNCO>2.0.ZU;2-L
Abstract
A neutral bidentate P,N-ligand combining a hard dimethylamino nitrogen and a soft phosphine phosphorus donor affords the neutral trigonal bi pyramidal as well as the cationic square-planar nickel(II) complexes c is-[NiCl2(PMe(2)Ph)(PNMe(2))] and [NiCl(PMe(2)Ph)(PNMe(2))]PF6, respec tively, The latter species exhibits an appreciable catalytic activity in propylene oligomerization in the presence of Et(2)AlCl as co-cataly st.