Depth dependent nitridation enhanced diffusion (NED) of Sb was investi
gated by annealing Si(100) doping superlattice (DSL) structures in NH3
at 810-910 degrees C for 15-180 min. These multilayered DSLs consiste
d of six 10 nm wide Sb doping spikes spaced 100 nm apart. Antimony NED
, attributed to vacancy injection, indicated vacancy supersaturation v
alues of 3-5. From the spatial decay of Sb NED, lower bounds for vacan
cy diffusivities of (7.9+/-1.4)+/-10(-14), (1.2+/-0.2) x 10(-12), and
2.1 x 10(-11) cm(2)/s were obtained at 810, 860, and 910 degrees C, re
spectively. Evidence of trap limited vacancy diffusivity was observed.
(C) 1996 American Institute of Physics.