Dn. Perera et P. Harrowell, CONSEQUENCES OF KINETIC INHOMOGENEITIES IN GLASSES, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 54(2), 1996, pp. 1652-1662
Many of the physical pictures used to rationalize the phenomenology of
glassy dynamics rest upon a consideration of spatial fluctuations in
the relaxation kinetics of the glass-forming liquid. We examine the wi
re ranging consequences which flow from assuming the existence of tran
sient kinetic inhomogeneities. These consequences include: strong and
fragile behavior, two-step relaxation processes, nonlinear relaxation
following temperature jumps, spatially correlated kinetics and non-Gau
ssian behavior of incoherent processes. These general predictions are
explored in simulations in which relaxation is governed by diffusing d
efects.