ZnS layers are widely used in optics as high refractive index films in
multilayer coatings as well as for protective purposes. We have depos
ited ZnS coatings on different metal films to prevent their surface de
gradation when exposed to the ambient. In particular, magnesium is a v
ery active material that generates a diffusive oxide layer as soon as
it is removed from the vacuum chamber. Here we are presenting an optic
al characterization of the ZnS/Mg/ZnS/Glass system, using Spectrophoto
metry, and the Drude and Lorentz models for the dielectric function. T
o determine the type and strength of the interaction between the ZnS a
nd the Mg we performed a study of the interface using Auger electron s
pectroscopy and scanning electron microscopy.