We investigated the native oxidation of ion-implanted Si(100) surfaces
in anticipation of a future necessity for controlling native oxidatio
n during semiconductor device fabrication. Quantitative analysis of XP
S spectra was used to estimate SiO2 and SiO, thicknesses. Native oxida
tion of Si(100) wafers in which were implanted with As, P, B or Si was
examined. The results show that oxidation of As or P-implanted Si is
much faster than that of Si without implantation, however, no conclusi
ve difference was found between the oxidation rates of B or Si-implant
ed Si and that of Si without implantation. These results indicate that
native oxidation is influenced mainly by the species of implanted ion
s. Neither ion-implantation induced defects nor surface roughness was
found to have major effect on the native oxidation rate.