Gallium nitride films have been grown by microwave plasma assisted las
er induced chemical vapor deposition at about 550 degrees C. Trimethyl
gallium and ammonia served as group III and group V sources, respectiv
ely. Ammonia was introduced into the reaction chamber by two separate
lines. In one of the lines, ammonia first passed through a microwave c
avity where it could be ionized into a plasma, before being delivered
to the chamber. An ArF excimer laser (193 nm) was used to photodissoci
ate the ammonia and trimethylgallium introduced through the other line
. The room temperature electron concentration and Hall mobility of the
films were measured to be in the range 10(15)-10(16) cm(-3) and up to
200 cm(2)/Vs, respectively. Strong room temperature near-band photolu
minescence detected from the films indicated their good optical qualit
y. The photoconductive decay of photocarriers was also investigated.