INTERACTIONS IN BINARY-MIXTURES - PARTIAL STRUCTURE FACTORS IN MIXTURES OF SODIUM DODECYL-SULFATE MICELLES AND COLLOIDAL SILICA

We have investigated the stability of a mixed colloidal system of sodi um dodecyl sulfate (SDS) micelles and colloidal silica (Ludox TM). The colloidal silica is stably dispersed in water by virtue of its surfac e charge, but at SDS concentrations greater than 0.45 M the silica par ticles slowly aggregate. This transition is monitored with small angle neutron scattering (SANS) using a solvent contrast variation techniqu e. Partial structure factors for the binary mixture are extracted from the SANS data using an optimization-regularization procedure. Knowled ge of the partial structure factors in this asymmetric mixture (the Lu dox radius is five times that of the micelles) allows us to determine the three pair interaction potentials. Model calculations for a multic omponent sticky hard sphere fluid are fitted to the experimental parti al structure factors, thereby quantifying all three pair interaction p otentials (which are potentials of mean force). For a fixed silica vol ume fraction of 0.063, attractive interactions between the silica part icles increase as the volume fraction of micelles is increased from 0. 021 to 0.181. The micelles interact with a screened Coulomb repulsion that decreases in strength as the micelle concentration increases. The micelle-Ludox interaction has not been previously measured, and can b e modeled as a hard-sphere-charged-sphere interaction for all of the m ixture compositions studied. (C) 1996 American Institute of Physics.