PHENYLSELENIUM TRICHLORIDE, PREPARATION AND USE AS A VINYLIC CHLORINATION REAGENT

Authors
STUHRHANSEN N HENRIKSEN L KODRA JT
Citation
N. Stuhrhansen et al., PHENYLSELENIUM TRICHLORIDE, PREPARATION AND USE AS A VINYLIC CHLORINATION REAGENT, Synthetic communications, 26(18), 1996, pp. 3345-3350
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
26
Issue
18
Year of publication
1996
Pages
3345 - 3350
Database
ISI
SICI code
0039-7911(1996)26:18<3345:PTPAUA>2.0.ZU;2-L
Abstract
Phenylselenium trichloride (1) is prepared from benzeneseleninic acid (2) and thionyl chloride and used to effect vinylic chlorination, viz. the conversion of 3-chloro-2-chloromethyl-1-propene (4) into 2-chloro methyl-1,3-dichloropropene (3).