J. Zoric et al., CURRENT DISTRIBUTION IN ALUMINUM ELECTROLYSIS CELLS WITH SODERBERG ANODES .2. MATHEMATICAL-MODELING, Journal of Applied Electrochemistry, 26(8), 1996, pp. 795-802
The current distribution in an aluminium electrolysis cell with a Sode
rberg anode was calculated to supplement measured data (Part I of this
study). A numerical method based on the conservative scheme was used.
A 2D cross section of a commercial cell was considered and the electr
ic fields in the anode, cathode and the electrolyte were considered un
der steady state conditions. Four different approximations of a curvil
inear boundary were proposed. The overvoltage for both electrodes was
introduced. The current density decreased along the side of the anode
from the nominal value 0.8 A cm(-2) on the underside to 0.26 A cm(-2)
in the upper part near the surface of the electrolyte. The calculated
current density along the side of the Soderberg anode for all the appr
oximations was compared with the measured data, and the agreement was
within 10 to 15%. In the curved part of the anode the differences betw
een measured and calculated values were 20-28%; but in this region the
accuracy of the experimental data was in the same range. Also the fin
ite element method was used for the comparison of the calculated curre
nt density.