H. Sugie et al., IDENTIFICATION OF THE AGGREGATION PHEROMONE OF THE BROWN-WINGED GREENBUG, PLAUTIA-STALI SCOTT (HETEROPTERA, PENTATOMIDAE), Applied Entomology and Zoology, 31(3), 1996, pp. 427-431
Identification of the aggregation pheromone responsible for the aggreg
ation phenomena of the brown-winged green bug, Plautia stali Scott (He
teroptera: Pentatomidae) was attempted. Volatiles collected from adult
males which attracted adults showed attraction activity under field c
onditions. Volatiles were then collected from a total of 180,000 adult
males and the activity of the fractionated samples was field tested u
sing water pan traps. A mixture of hexane and 5% ether in hexane fract
ions from Florisil LC showed attraction activity, and this was further
purified with HPLC and GC. By GC-MS and NMR analysis (COSY), the chem
ical structure of the active compound was identified as methyl (E,E,Z)
-2,4,6-decatrienoate. The attraction activity of the synthesized compo
und of this structure was confirmed by field tests.