2-FUNCTIONALIZED ALLYL TRIS(TRIMETHYLSILYL)SILANES AS RADICAL-BASED ALLYLATING AGENTS

Authors
CHATGILIALOGLU C FERRERI C BALLESTRI M CURRAN DP
Citation
C. Chatgilialoglu et al., 2-FUNCTIONALIZED ALLYL TRIS(TRIMETHYLSILYL)SILANES AS RADICAL-BASED ALLYLATING AGENTS, Tetrahedron letters, 37(35), 1996, pp. 6387-6390
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
35
Year of publication
1996
Pages
6387 - 6390
Database
ISI
SICI code
0040-4039(1996)37:35<6387:2ATARA>2.0.ZU;2-#
Abstract
Radical allylations with 2-functionalized allyl tris(trimethylsilyl)si lanes occur under mild conditions in good to excellent yield provided that the radical precursor and the silane have the appropriate electro nic pairing. These reactions offer tin-free alternatives for tansforma tions that are currently conducted with allylstannanes. Copyright (C) 1996 Elsevier Science Ltd