The oxidized tapioca starch, which was prepared by oxidizing with sodi
um hypochlorite at pH 10, exhibited the emulsificating ability. The mi
xture of the oxidized starch and sugar esters or casein also had a sim
ilar emulsificating ability. The addition of electrolytes such as salt
or base, except acid, did not affect the ability. The ability depende
d on the degree of oxidization of starch concentration. The emulsifica
ting ability was not considered to come from the high viscosity of the
starch solution but to come from the electrostatic repulsion of carbo
xy groups formed on the oxidized starch chains.