Ht. Skinner et al., REMOTE RAMAN MICROIMAGING USING AN AOTF AND A SPATIALLY COHERENT MICROFIBER OPTICAL PROBE, Applied spectroscopy, 50(8), 1996, pp. 1007-1014
A fiber-optic Raman microimaging probe is described that is suitable f
or acquiring high-spatial-resolution Raman images in sampling situatio
ns with no clear line of sight. A high-power near-infrared diode laser
combined with an acousto-optic tunable filter and a spatially coheren
t optical fiber bundle allow fluorescence-free Raman images of remotel
y located samples to be acquired at distances up to several meters. Th
e feasibility of this technique is demonstrated with Raman images of (
1) a pellet containing a mixture of a highly scattering sample, bis-me
thylstyrylbenzene (BMSB), KCl, and graphite, and (2) a partially graph
itized diamond. These images clearly show phase boundaries over an are
a of approximately 0.1 mm(2) with similar to 4-mu m resolution.