A theoretical and practical framework of different problems has been d
iscussed to explain advantages and limitations of techniques based on
electrical sensing methods which are consistent to implement structure
evaluation of materials. The term ''structure evaluation'' is general
ly used here to mean extracting the quantitative information of intere
st of a material or an object to be examined from a physical measureme
nt, or more typically from a set of physical measurements, that themse
lves may be only indirectly related to the quantitative information de
sired. The paper emphasizes the point that the structure evaluation is
a typical inverse problem and as such is made more difficult, since i
nverse problems are characteristically ill-conditioned, that is, small
errors in the measurement typically lead to large errors in the solut
ion. Use of physically motivated a priori information to diminishing s
uch ill-conditioning is discussed. Features of updated electrical sens
ing methods, particularly those used for nondestructive testing (NDT)
are considered. Potential advantages of the electrical methods compare
d to other NDT techniques are that they offer inexpensive, safe, nonha
rmful, and fast testing. Some novel achievements including excitation
with a number of complex electric field excitation patterns on the obj
ect together with computer-assisted information acquisition have consi
derably extended both the potential and the scope of the electrical me
thods which will still be recognized, In order to present an up-to-dat
e perspective, some conceptual and methodologic aspects have been cons
idered for two structure evaluation problems, i.e., for generating a)
algorithms for determining structural parameters of materials, such as
density, moisture content, polymerization degree, etc., from dielectr
ic spectra; b) tomographic cross-sectional maps of electrical paramete
rs of the object to be examined.