N-Phthalimido-substituted polyimides soluble in organic solvents were
prepared by reaction of bis(o-phenylenediamines), which are the best k
now chloral derivatives, with bis(phthalic anhydride)s folio wed by th
e reaction with phthalic anhydride and catalytic imidization of the sy
nthesized prepolymers. Polyimides combine high thermal stability and f
ire-resistance with good processibility and capability of forming cros
s-linked structures upon heating.