CATALYTIC INEQUIVALENCE OF LOW-MOLECULAR- MASS AND HIGH-MOLECULAR-MASS ADDUCTS OF 2,2,6,6-TETRAMETHYLPIPERIDINYLOXY IN RADICAL POLYMERIZATION OF FLUOROALKYL METHACRYLATES

Authors
ILIN AA SMIRNOV BR RYBIN NV GOLIKOV LV MOGILEVICH MM NO VB
Citation
Aa. Ilin et al., CATALYTIC INEQUIVALENCE OF LOW-MOLECULAR- MASS AND HIGH-MOLECULAR-MASS ADDUCTS OF 2,2,6,6-TETRAMETHYLPIPERIDINYLOXY IN RADICAL POLYMERIZATION OF FLUOROALKYL METHACRYLATES, Vysokomolekularnye soedinenia. Seria A, 38(6), 1996, pp. 1080-1083
Citations number
8
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
38
Issue
6
Year of publication
1996
Pages
1080 - 1083
Database
ISI
SICI code
0507-5475(1996)38:6<1080:CIOLMA>2.0.ZU;2-N
Abstract
The kinetics of AIBN-initiated polymerization of terafluoropropyl meth acrylate in the presence of iminoxyl radical 2,2,6,6-tetramethylpiperi dinyloxy. Deviations of the kinetics from that of catalytic secondary inhibition that are observed after the elapse of induction period are caused by inequivalence of low- and high-molecular-mass adducts of the iminoxyl radical, the catalytic activity of the high-molecular-mass a dduct being stronger.