PREPARATIVE, ELECTROENZYMATIC REDUCTION OF NAD(-COATED GRAPHITE FELT ELECTRODE COIMMOBILIZING ION-PAIRED METHYL VIOLOGEN-CATION-EXCHANGE POLYMER AND DIAPHORASE() TO NADH ON A THIN POLY(ACRYLIC ACID) LAYER)

Authors
KASHIWAGI Y YANAGISAWA Y SHIBAYAMA N NAKAHARA K KURASHIMA F ANZAI J OSA T
Citation
Y. Kashiwagi et al., PREPARATIVE, ELECTROENZYMATIC REDUCTION OF NAD(-COATED GRAPHITE FELT ELECTRODE COIMMOBILIZING ION-PAIRED METHYL VIOLOGEN-CATION-EXCHANGE POLYMER AND DIAPHORASE() TO NADH ON A THIN POLY(ACRYLIC ACID) LAYER), Chemistry Letters, (12), 1996, pp. 1093-1094
Citations number
32
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
12
Year of publication
1996
Pages
1093 - 1094
Database
ISI
SICI code
0366-7022(1996):12<1093:PERONG>2.0.ZU;2-2
Abstract
A thin poly(acrylic acid) layer-coated graphite felt electrode coimmob ilizing ion-paired methyl viologen - cation-exchange polymer and diaph orase was prepared and applied to preparative electroenzymatic reducti on of NAD(+) in phosphate buffer at constant potential of - 0.80 V vs. SCE. The electrode was stable for the reaction and yielded NADH quant itatively in 97.8% current efficiency.