Recent advances have been made in research on carbon molecular sieve a
nd zeolite adsorbents used in the non-cryogenic production of nitrogen
and oxygen. Preparation methods that allow stringent control of poros
ity, density, and surface properties have resulted in carbon molecular
sieve adsorbents with higher capacity and selectivity for nitrogen pr
oduction. Recently, a new generation of mixed-cation zeolite adsorbent
s with high N-2/O-2 selectivity and improved stability has been develo
ped for oxygen production.