Mc. Ramusino et al., H-1-NMR AND UV SPECTROSCOPIC STUDY OF INCLUSION COMPLEX-FORMATION BETWEEN PYRIDOXINE AND BETA-CYCLODEXTRIN AND GAMMA-CYCLODEXTRIN, Journal of inclusion phenomena and molecular recognition in chemistry, 25(1-3), 1996, pp. 113-116
Inclusion complex formation between pyridoxine and beta- and gamma-cyc
lodextrins in aqueous solution has been investigated by H-1 NMR and UV
spectroscopy. Both complexes exhibited a 1:1 stoichiometry and the in
clusion process has been shown to perturb the equilibrium between the
lactim and the lactam tautomer of pyridoxine, with a preferential incl
usion of the former, less polar tautomer.