A continuously sampling, time-of-flight mass spectrometer has been use
d to measure relative species concentrations in a two-dimensional, hyd
rogen-air combustion wake at mainstream Mach numbers exceeding 5. The
experiments, in a free piston shock tunnel, yielded distributions of h
ydrogen, oxygen, nitrogen, water, and nitric oxide at stagnation entha
lpies ranging from 5.6 MJ kg(-1) to 12.2 MJ kg(-1) and at a distance o
f approximately 100 times the thickness of the initial hydrogen jet. T
he amount of hydrogen mixed in stoichiometric proportions was approxim
ately independent of the stagnation enthalpy, despite the fact that th
e proportion of hydrogen in the wake was increased with stagnation ent
halpy. Roughly 50% of the mixed hydrogen underwent combustion at the h
ighest enthalpy. The proportion of hydrogen reacting to water could be
approximately predicted using reaction rates based on mainstream temp
eratures.