An overview of photothermal deflection principles and applications is
given. The modeling of temperature distribution and the calculation of
deflection that is due to both the refractive-index gradient and the
thermal deformation of the sample are presented. Three configurations
usually employed are compared, and their respective advantages are dis
cussed in relation to their application. The calibration for absolute
measurement of absorption is detailed, showing that calibration limits
the accuracy of measurement. Some examples of specific information ob
tained by photothermal mapping of absorption are given. (C) 1996 Optic
al Society of America