SYNTHESIS, CHARACTERIZATION AND REACTIVITY OF EXO-NIDO-RH(PPH(3))(2)(ETA(5)-C(2)B(9)H(10)ME(2))]

Authors
TOPALOGLU I
Citation
I. Topaloglu, SYNTHESIS, CHARACTERIZATION AND REACTIVITY OF EXO-NIDO-RH(PPH(3))(2)(ETA(5)-C(2)B(9)H(10)ME(2))], Synthesis and reactivity in inorganic and metal-organic chemistry, 26(8), 1996, pp. 1295-1305
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
26
Issue
8
Year of publication
1996
Pages
1295 - 1305
Database
ISI
SICI code
0094-5714(1996)26:8<1295:SCAROE>2.0.ZU;2-G
Abstract
In this work, the reaction of the 16-electron species [Rh(eta(3)-C8H13 )(eta(5)-C(2)B(9)H(9)Me(2))] with PPh(3) was investigated and the prod uct, xo-nido-Rh(PPh(3))(2)(eta(5)-C(2)B(9)H(10)Me(2))], which is in an equilibrium with the close analogue was characterized by P-31 {H-1}, H-1, C-13 and B-11 NMR spectroscopy. A mechanism for the complex forma tion is suggested which is related to,the previously reported reaction s between the 16-electron complex and PR(3) (R = Me and Et) ligands.