STEREOCHEMISTRY OF MOLYBDENUM(II) PI-ALLYL COMPLEXES

Authors
JOSHI VS CHOWDHURY SK SARKAR A
Citation
Vs. Joshi et al., STEREOCHEMISTRY OF MOLYBDENUM(II) PI-ALLYL COMPLEXES, Proceedings of the Indian Academy of Sciences. Chemical sciences, 108(3), 1996, pp. 217-227
Citations number
35
Categorie Soggetti
Chemistry
Journal title
Proceedings of the Indian Academy of Sciences. Chemical sciences → ACNP
ISSN journal
02534134
Volume
108
Issue
3
Year of publication
1996
Pages
217 - 227
Database
ISI
SICI code
0253-4134(1996)108:3<217:SOMPC>2.0.ZU;2-T
Abstract
The stereochemistry of molybdenum(II) pi-allyl complexes is generally governed by intramolecular interactions between the ligand and the all yl group substituents. Interatomic repulsions are normally dominant. H owever, weak, attractive interactions may sometimes dictate conformati onal preferences. Examples include new organomolybdenum complexes cont aining pyrazole-derived chelating ligands. Structural information has been obtained from NMR spectroscopy and single crystal X-ray diffracti on.