KINETIC RESOLUTION OF 1,2,3,4-TETRAHYDRO[1]NAPHTHYL HYDROPEROXIDE BY DECOMPOSITION IN THE PRESENCE OF A CHIRAL MN(III) SALEN COMPLEX

Authors
HAMANN HJ HOFT E
Citation
Hj. Hamann et E. Hoft, KINETIC RESOLUTION OF 1,2,3,4-TETRAHYDRO[1]NAPHTHYL HYDROPEROXIDE BY DECOMPOSITION IN THE PRESENCE OF A CHIRAL MN(III) SALEN COMPLEX, Tetrahedron : asymmetry, 7(8), 1996, pp. 2217-2218
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
7
Issue
8
Year of publication
1996
Pages
2217 - 2218
Database
ISI
SICI code
0957-4166(1996)7:8<2217:KRO1HB>2.0.ZU;2-8
Abstract
The kinetic resolution of 1,2,3,4-tetrahydro[1]naphthyl hydroperoxide by decomposition in the presence of Jacobsen catalyst has been investi gated. An enantiomeric excess up to 45% was obtained for the remaining hydroperoxide as well as for the alcohol formed. Copyright (C) 1996 P ublished by Elsevier Science Ltd