K. Fujishiro et Y. Uesu, OPTICAL AND X-RAY STUDIES ON THE LOW-TEMPERATURE PHASE-TRANSITION OF BA2NANB5O15, Journal of physics. Condensed matter, 8(35), 1996, pp. 6435-6443
Low-temperature phase transitions of Ba2NaNb5O15 with non-stoichiometr
ic composition were investigated using a polarization microscope and x
-ray diffractometer. Both apparatuses were equipped with a specially d
esigned low-temperature cryostat which enabled us to measure the biref
ringence down to 4 K and x-ray reflections down to 20 K. Ferroelastic
domain structure was observed to persist even at 4 K. Birefringence De
lta n(ab) and pure shear x(12) show a peak at about 200 K and drop ste
eply at 110 K but do not vanish below 110 K. These facts indicate that
the phase below 110 K is not re-entrant to the tetragonal 4 mm phase.
The quite long relaxation process observed in birefringence and the a
ppearance of a new reflection in the x-ray diffraction experiment indi
cate that the quasi-tetragonal region appears at 110 K and develops wi
th long relaxation time.