R. Klein et G. Nagele, STATIC AND DYNAMIC SCATTERING BY CONCENTRATED SYSTEMS - THEORY, Current opinion in colloid & interface science, 1(1), 1996, pp. 4-10
Significant progress has been made concerning the understanding of sev
eral aspects of microstructure and dynamics of concentrated suspension
s. Among these aspects are the proper description of the small-angle p
eak observed in scattering from aggregating colloids, the theories for
the phase behaviour of colloid-polymer mixtures as well as of binary
hard-sphere suspensions and the quantitative calculation of the effect
s of hydrodynamic interaction on the short dynamics of charge-stabiliz
ed colloids. There have been several theoretical and experimental inve
stigations on possible generalizations of the Stokes Einstein relation
to concentrated suspensions. Mode-coupling theory for the glass trans
ition describes nearly monodisperse hard-sphere systems well, but is f
ound to fail partially for other systems.