SILICON AS A CONTROLLING ELEMENT FOR REGIOSELECTIVE ENE REACTION OF DIETHYL AZODICARBOXYLATE WITH (HOMO)ALLYLIC SILANES - APPLICATIONS TO THESYNTHESIS OF CYCLIC 1,2-DINITROGEN COMPOUNDS

Authors
SARKAR TK GHORAI BK DAS SK GANGOPADHYAY P RAO PSVS
Citation
Tk. Sarkar et al., SILICON AS A CONTROLLING ELEMENT FOR REGIOSELECTIVE ENE REACTION OF DIETHYL AZODICARBOXYLATE WITH (HOMO)ALLYLIC SILANES - APPLICATIONS TO THESYNTHESIS OF CYCLIC 1,2-DINITROGEN COMPOUNDS, Tetrahedron letters, 37(36), 1996, pp. 6607-6610
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
36
Year of publication
1996
Pages
6607 - 6610
Database
ISI
SICI code
0040-4039(1996)37:36<6607:SAACEF>2.0.ZU;2-2
Abstract
The reaction of diethyl azodicarboxylate with homoallylic silanes capa ble of two modes of reaction give ene adducts by preferential abstract ion of allylic hydrogens nearer the silyl group. This regioselectivity has been exploited in the synthesis of some cyclic hydrazine derivati ves. Copyright (C) 1996 Published by Elsevier Science Ltd