AEROBIC CATALYTIC EPOXIDATION OF UNFUNCTIONALIZED OLEFINS USING A NEW(SALEN) MANGANESE(III) COMPLEX BEARING A SESQUITERPENE SALICYLALDEHYDE DERIVATIVE

Authors
FERNANDEZ I PEDRO JR DELASALUD R
Citation
I. Fernandez et al., AEROBIC CATALYTIC EPOXIDATION OF UNFUNCTIONALIZED OLEFINS USING A NEW(SALEN) MANGANESE(III) COMPLEX BEARING A SESQUITERPENE SALICYLALDEHYDE DERIVATIVE, Tetrahedron, 52(36), 1996, pp. 12031-12038
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
36
Year of publication
1996
Pages
12031 - 12038
Database
ISI
SICI code
0040-4020(1996)52:36<12031:ACEOUO>2.0.ZU;2-L
Abstract
A chiral (salen) manganese (III) complex 1 bearing a sesquiterpene sal icylaldehyde and (RP)-1,2-clohexanediamine moieties has been prepared. This complex catalyses the epoxidation of unfunctionalized olefins wi th iodosylbenzene and molecular oxygen/pivalaldehyde as terminal oxida nts. In all cases the chemical yield was high although the enantiomeri c excess obtained were low. Copyright (C) 1996 Elsevier Science Ltd.