Spectroscopic diagnostic methods such as laser-induced fluorescence (L
IF) and spontaneous Raman scattering are combined to perform point mea
surement of nitric oxide, hydroxyl, major species concentrations, and
temperature in a turbulent hydrogen-air diffusion flame. The experimen
tal procedure is presented and a brief introduction to the modeling an
d numerical calculation of the turbulent combustion system is given. T
he assumption of chemical equilibrium for the calculation of nitric ox
ide and hydroxyl concentrations is found to be insufficient. The intro
duction of the progress variable leads to a significant improvement in
prediction abilities of the model.