T. Shinzawa et al., BARRIER LAYERLESS SUBMICRON ALUMINUM-DAMASCENE INTERCONNECTION USING ALUMINUM CHEMICAL-VAPOR-DEPOSITION WITH A NEW NUCLEATION METHOD, Electronics & communications in Japan. Part 2, Electronics, 79(5), 1996, pp. 88-96
Barrier layerless submicron damascene interconnection has been realize
d by using a combination of novel aluminum chemical vapor deposition (
Al-CVD) and chemical mechanical polishing (CMP) techniques. A new nucl
eation method with tetrakis-dimethyl-amino titanium (TDMAT) gas pretre
atment has enabled Al-CVD to fill trenches without using a barrier lay
er which causes high resistivity. As a result, this technology achieve
d Al damascene interconnections with resistance as low as 600 Omega/cm
with half-micron wide line and an aspect ratio of 3. This line resist
ance is one-third of that for a conventional reactive ion-etched Al li
ne with an aspect ratio of 1.