REACTIONS OF KETENIMINES WITH ARENE-SULFANYL AND ARENE-SELANYL CHLORIDES - A GENERAL-ROUTE TO SECONDARY AMIDE DERIVATIVES AND A NEW SYNTHESIS OF C-SULFANYL-KETENIMINES AND C-SELANYL-KETENIMINES

Authors
MCCARTHY DG MCCUTCHEON PO SHEEHAN DP
Citation
Dg. Mccarthy et al., REACTIONS OF KETENIMINES WITH ARENE-SULFANYL AND ARENE-SELANYL CHLORIDES - A GENERAL-ROUTE TO SECONDARY AMIDE DERIVATIVES AND A NEW SYNTHESIS OF C-SULFANYL-KETENIMINES AND C-SELANYL-KETENIMINES, Journal of the Chemical Society. Perkin transactions. I, (20), 1994, pp. 2899-2901
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
20
Year of publication
1994
Pages
2899 - 2901
Database
ISI
SICI code
0300-922X(1994):20<2899:ROKWAA>2.0.ZU;2-0
Abstract
Ketenimines 1, react with arene-sulfanyl and -selanyl chlorides to giv e the imidoyl chlorides 3 that either yield the substituted amides 4 u pon solvolysis in aqueous acetone, or the C-sulfanyl- and C-selanyl-ke tenimines 5 by dehydrochlorination with triethylamine.