Gram quantities of molten aluminum droplets at temperatures up to 1973
K are forced to interact with water under sustained pressure pulses o
f up to 40.8 MPa in a hydrodynamic shock tube. Conditions are identifi
ed under which the thermal interaction (physical regime) develops into
chemical ignition and total combustion events. This, and the absence
of catastrophic breakup in the physical regime, raises some very inter
esting questions with regard to the sequence of events during large-sc
ale aluminum-water explosions.