N. Sonoda et al., LOW-TEMPERATURE GROWTH OF ORIENTED SILICON-CARBIDE ON SILICON BY REACTIVE HYDROGEN PLASMA SPUTTERING TECHNIQUE, JPN J A P 2, 35(8B), 1996, pp. 1023-1026
Highly oriented beta-SiC film is prepared on (100) Si substrate at 800
degrees C by reactive hydrogen plasma sputtering of a ceramic SiC tar
get. The highly oriented beta-SiC film can be growth on (100) Si subst
rate without void formation at the SiC film/Si interface. Hydrogen pla
sma etching of the growing film plays an important role in the growth
of the oriented beta-SiC films. Voids at the SiC film/Si interface are
formed at a temperature of about 800 degrees C due to the reaction of
SiC film with Si substrate. Also, a thin amorphous buffer layer of 5
nm thickness is formed at the SiC film/Si interface. The results of th
is study indicate that the buffer layer can be eliminated by a suitabl
e surface treatment of Si substrate before film growth.