SYNTHESIS, PHOTOPHYSICS AND ELECTROCHEMISTRY OF [AU-2(DPPF)R(2)] [DPPF=FE(ETA-C(5)H(4)PPH(2))(2) - R=ALKYL, ARYL OR ALKYNYL] - CRYSTAL-STRUCTURE OF [AU-2(DPPF)(C16H9)(2)] (C16H9=PYREN-1-YL)

Authors
YAM VWW CHOI SWK CHEUNG KK
Citation
Vww. Yam et al., SYNTHESIS, PHOTOPHYSICS AND ELECTROCHEMISTRY OF [AU-2(DPPF)R(2)] [DPPF=FE(ETA-C(5)H(4)PPH(2))(2) - R=ALKYL, ARYL OR ALKYNYL] - CRYSTAL-STRUCTURE OF [AU-2(DPPF)(C16H9)(2)] (C16H9=PYREN-1-YL), Journal of the Chemical Society. Dalton transactions, (16), 1996, pp. 3411-3415
Citations number
42
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
16
Year of publication
1996
Pages
3411 - 3415
Database
ISI
SICI code
0300-9246(1996):16<3411:SPAEO[>2.0.ZU;2-X
Abstract
A series of organometallic complexes [Au-2(dppf)R(2)] [dppf = Fe(eta-C (5)H(4)PPh(2))(2); R = Me, Ph, 1-naphthyl, 9-anthryl, pyren-1-yl (C16H 9), C=CPh or C=CBu(t)] have been synthesized; Their photophysical and electrochemical properties have been studied. Both excimer and exciple x formation are evidenced in[Au(dppf)(2)(C16H9)(2)]. The crystal struc ture of the latter has been determined.