The vibrational and electronic excitations of Na atoms chemisorbed on
Mo(100) have been investigated with high-resolution electron energy lo
ss spectroscopy (HREELS). An intense loss mode at 19 meV is assigned t
o perpendicular vibrations of the Na atoms. While the frequency of thi
s mode does not shift with coverage within +/-1 meV, the intensity is
strongly coverage dependent, becoming too weak to be observed above th
e work function minimum (similar to 0.5 ML). The absence of a frequenc
y shift is contrary to the expectations of the Gurney model as well as
more recent theoretical calculations. Work-function changes, the cove
rage dependence of the dynamic charge and low coverage electronic loss
es are all accounted for by the phenomenological Newns-Anderson model.