Na. Kotov et al., ULTRATHIN GRAPHITE OXIDE-POLYELECTROLYTE COMPOSITES PREPARED BY SELF-ASSEMBLY - TRANSITION BETWEEN CONDUCTIVE AND NONCONDUCTIVE STATES, Advanced materials, 8(8), 1996, pp. 637
Ultrathin films of graphite-polymer composites, which are required for
sensors applications, are the target of the work reported here. The p
reparation and characterization of ultrathin films composed of self-as
sembled graphite oxide (GO) platelets and polyelectrolytes are describ
ed, followed by the in situ reduction of GO to a conductive graphite-l
ike state (G) by chemical and electrochemical methods. Particular atte
ntion is paid to the non-conductive to conductive transition that occu
rs on reduction and the behavior of incorporated CdS particles.