Kd. Jandt et al., MICROSTRUCTURE OF BLOCK-COPOLYMER REINFORCED INTERFACES OBSERVED WITHFRICTIONAL FORCE MICROSCOPY, Advanced materials, 8(8), 1996, pp. 660
The microstructure of block copolymer-reinforced interfaces of homopol
ymers has been studied by frictional force microscopy (FFM). The FFM m
icrograph in the Figure shows details, e.g., lamellar branching, of a
poly(styrene)/poly(2-vinylpyridine) (PS/PVP) homopolymer interface rei
nforced with a PVP-PS-PVP triblock copolymer. An explanation for the n
eed to ''develop'' the FFM image is proposed and the advantages of FFM
over TEM are discussed.