The ability to create unique nanoscale structures and to control the m
orphology of those structures with external fields (such as shear) has
led to a blossoming of interest in block copolymer solutions and melt
s. The interrelations between shear history, morphology and rheology a
re actively being explored using experiments and computer simulation,
although much remains to be done. Indeed, recent diffusion and rheolog
y experiments indicate that even the disordered phase of these materia
ls is not really understood.