Micellar catalysis provides a means for synthesizing novel and convent
ional materials in aqueous media, resulting in improved reaction rates
and eliminating the need for organic solvents. Recent developments in
clude application of micellar catalysis to complex multiphase systems
in which the surfactant plays multiple roles and interphase transport
effects are often important. Experimental and theoretical studies have
provided an improved understanding of competitive counterion binding,
the effects of reactive and inert solubilizates, functionalized surfa
ctants, and the use of surfactant aggregates as reaction templates.