AN UNIFIED QUANTITATIVE APPROACH TO ELECTROLYTIC SYSTEMS

Citation
T. Michalowski et al., AN UNIFIED QUANTITATIVE APPROACH TO ELECTROLYTIC SYSTEMS, Chemia Analityczna, 41(4), 1996, pp. 667-685
Citations number
32
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00092223
Volume
41
Issue
4
Year of publication
1996
Pages
667 - 685
Database
ISI
SICI code
0009-2223(1996)41:4<667:AUQATE>2.0.ZU;2-O
Abstract
Balancing of electrolytic systems is applied both for equilibrium anal ysis and for kinetic purposes. The advantages of such approach were co mpared with one based on the reaction notation. The equilibrium analys is was the basis to introduce the unified equivalence mass concept and to evaluate the relative systematic error in a titrimetric analysis; it enables the best a priori conditions for appropriate titrations to be chosen. Balancing of kinetic systems provides a formulation adaptab le, among others, to oscillating systems of the Belousov-Zhabotinsky t ype.