THE REACTION OF SYRINGOL WITH CHLORINE DIOXIDE

Authors
MCKAGUE AB GREY A
Citation
Ab. Mckague et A. Grey, THE REACTION OF SYRINGOL WITH CHLORINE DIOXIDE, Journal of wood chemistry and technology, 16(3), 1996, pp. 249-259
Citations number
9
Categorie Soggetti
Materials Science, Paper & Wood
Journal title
Journal of wood chemistry and technology → ACNP
ISSN journal
02773813
Volume
16
Issue
3
Year of publication
1996
Pages
249 - 259
Database
ISI
SICI code
0277-3813(1996)16:3<249:TROSWC>2.0.ZU;2-2
Abstract
Syringol 2 (R=H) reacted with chlorine dioxide to give the dione 7 and its benzilic acid rearrangement product 8a as the major products. Oth er products were the dimethoxybenzoquinones 3a and 3b, 3-chlorosyringo l 4b, chlorocyclopropenone 5, 2-furoic acid 6a and the dichloromethyle nefuranones 10a and 10b. Two samples of effluent from chlorine dioxide bleaching contained the dione 7, while one sample contained the furan one 10a, and one contained the isomer 10b.